SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product Identifiers

Product Name:Arocos-PAA natural

CAS Number:100-09-4

EINECS Number:202-818-5

1.2 Other means of identification

Other names  4-methoxybenzoic acid;p-Anisic acid

1.3 Recommended use of the chemical and restriction on use

Identified uses

Food additives->Flavoring agents;Cosmetic ingredient

Uses advised against

no data available

1.4 Details of the supplier of the safety data sheet

Company:

Aromaholly Chemical (Jining) Co.,Ltd

No.1 Northern Central Road, Jining New Material Industry Park, Jinxiang 272211, China

Telephoner:0086-0537-8921999

E-mail:[email protected]

1.5 Emergency telephone number

Telephoner:

0086-0537-8921999

 

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Acute toxicity – Oral, Category 4

Skin irritation, Category 1

Skin irritation, Category 1

2.2 GHS label elements, including precautionary statements

Pictogram(s) Signal word

Warning Hazard statement(s)

H302 Harmful if swallowed

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation Precautionary statement(s)

Prevention

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash hands [and …] thoroughly after handling.

P264+P265 Wash hands [and …] thoroughly after handling. Do not touch eyes.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P301+P312 IF SWALLOWED: call a POISON CENTER/doctor/… IF you feel unwell.

P302+P352 IF ON SKIN: wash with plenty of water/…

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses if present and easy to do – continue rinsing.

P312 Call a POISON CENTER or doctor/… if you feel unwell.

P321 Specific treatment (see … on this label).

P330 Rinse mouth.

P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

P337+P313 IF eye irritation persists: Get medical advice/attention.

P362: Take off contaminated clothing.

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and producer characteristics at time of

disposal.

2.3 Other hazards which do not result in classification

no data available

 

SECTION 3: Composition/information on ingredients

Product Name:Arocos-PAA natural

Chemical name:4-methoxybenzoic acid

Molecular Formula:C8H8O3

CAS Number:100-09-4

EC Number 202-818-5

Molecular Weight: 152.15 g/mol

Concentration 99%-100%

SECTION 4: First-aid measures

4.1  Description of necessary first aid measuresGeneral advice:

Consult a physician.Show this safety data sheet to the doctor in attendance.

If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact: Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

 

SECTION 5: Firefighting measures

Flammable properties

Flash point

185 °C (365 °F) – closed cup

Ignition temperature

no data available

5.1 Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Extinguishing media which shall not be used for safety reasons

None known. Use extinguishing measures that are appropraite to local circumstances and the surrounding

environment.

5.3 Specific hazards during firefighting

Risks of dust explosion.

5.4 Special protective equipment for firefighters

Special protective equipment for fire-fighters. Self contained breathing apparatus (EN 133).

5.5 Further information: In the event of fire and/or explosion do not breathe fumes

Cool containers / tanks with water spray.SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing dust.

6.2 Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the

environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

6.4 Additional advice

no data available

 

SECTION 7: Handling and storage

7.1 Advice on safe handling

Electrical bonding of pneumatic conveyor. Earth the equipment. Blanket with inert gas.

7.2 Advice on protection against fire and explosion

Protect from moisture. Avoid dust formation. Avoid contact with water. Provide adequate ventilation.

7.3 Requirements for storage areas and containers

Recommended:Protect against light. Keep away from open flames, hot surfaces and sources of ignition. Keep

container tightly closed and dry.

Incompatible products: alkalis and caustic products. Oxidizing materials.

Packaging: Store in original container. Flexible container lined with a plastic film. Paper bag lined with a plastic film.

7.4 Advice on common storage

Recommended: Stainless steel. Plastic materials (polyethylene, polypropylene).

Not suitable: Certain plastic materials. Steel.

 

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available8.2

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under

appropriate government standards such as NIOSH (US) or EN 166(EU

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching

glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in

accordance with applicable laws and good laboratory practices. Wash and dry hands.

Body protection

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the

concentration and amount of the dangerous substance at the specific workplace

Respiratory protection

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle r (US) or type ABEKP2 (EU EN 143)

respirator cartridges. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU)

Thermal hazards

no data available

SECTION 9: Exposure controls/personal protection

Information on basic physical and chemical properties

Physical state

Solid 20°C and 1013 hPa

Colour

White-pale yellow

Odour

Characteristic

Melting point/range

182 – 185 °C (360 – 365 °F) at 101 325 Pa

Boiling point/range

275 – 280 °C (527 – 536 °F) at 101 325 Pa

Flammability

Not classified.

Upper explosion limit

Based on its chemical structure, the substance is not expected to have

explosive properties and it is therefore not classified as explosive according

to the CLP Regulation (EC) No. 1272/2008.

Lower explosion limit

Flash point

185 °C (365 °F) at 101 325 Pa

Ignition temperature

Not determined.

Decomposition temperature

Not determined.

pH

Not applicable.

Kinematic Viscosity

Not applicable.

Solubility in water

530mg/L at 37 °CPartition coefficient octanol/water

LogPow = -0.498 (octanol)

Vapour pressure

No data available

Density

No data available

Relative vapour pressure

No data available

Particle characteristics

No data available

 

SECTION 10: Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

Incompatible products.

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

Thermal decomposition can lead to release of irritating gases and vapors, Carbon monoxide (CO), Carbon dioxide

(CO2)

 

SECTION 11: Toxicological information

Acute toxicity

No data availablep-Anisic acid

Inhalation: No data available(p-Anisic acid)

LD50 Subcutaneous – Mouse – 400 mg/kg(p-Anisic acid)

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicityno data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

STOT-single exposure

no data available

Bioaccumulative potential

no data available

Aspiration hazard

no data available

 

SECTION 12: Ecological information

12.1 Toxicity

no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessm

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic

(PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

no data available

 

SECTION 13: Disposal considerations

13.1 Disposal methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a

combustible solvent and burn in a chem scrubber.Contaminated packaging

Dispose of as unused product.

 

SECTION 14: Transport information

14.1 UN Number

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.2 UN Proper Shipping Name

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.3 Transport hazard class(es)

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.4 Packing group, if applicable

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.5 Environmental hazards

ADR/RID: No IMDG: No IATA: No

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to IMO instruments

no data available