Product Name : 바닐린
Physical State : Solid
Project number: P2016040701
Version No:1.0
Safety Data Sheet (Conforms to Regulation (EC) No 1907/2006 and Regulation (EC) No 2015/830)
Issue Date:11/04/2016
S.REACH.DEU.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
1.1.Product Identifier
Product name 바닐린
Synonyms Chemical formula C8H8O3
Other means of identification Not Available
CAS number 121-33-5
EC number 204-465-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
used as fragrance in cosmetic and household products; used as food flavour
Uses advised against
Not Applicable
SECTION 2 HAZARDS IDENTIFICATION
2.1.Classification of the substance or mixture
Classification according to regulation (EC) No 1272/2008 [CLP]
Eye Irritation Category 2
2.2. Label elements Continued…
4-Hydroxy-3-methoxy-benzaldehydeNot Applicable
Not Applicable
CLP label elements SIGNAL WORD WARNING Hazard statement(s) H319
Causes serious eye irritation.
Supplementary statement(s)
Not Applicable
CLP classification (additional)
Not Applicable
Precautionary statement(s) Prevention
P280
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313
If eye irritation persists: Get medical advice/attention.
Precautionary statement(s) Storage
Precautionary statement(s) Disposal
2.3. Other hazards
REACh – Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
3.1.Substances
1.CAS No
2.EC No
3.Index No
4.REACH No
%[weight]
Classification according to regulation (EC) No 1272/2008 [CLP]
1.121-33-5
2.204-465-2
3.Not Available
≥ 99.5
Eye Irritation Category 2; H319
3.2.Mixtures
See ‘Information on ingredients’ in section 3.1
SECTION 4 FIRST AID MEASURES
4.1. Description of first aid measures
General
If skin or hair contact occurs:
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Immediately give a glass of water.
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
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ConfidentialSkin Contact
If skin or hair contact occurs:
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
Immediately give a glass of water.
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
5.1. Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
5.2. Special hazards arising from the substrate or mixture
Fire Incompatibility
None known.
5.3. Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered a significant fire risk, however containers may burn.
May emit corrosive fumes.
SECTION 6 ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
See section 8
6.2. Environmental precautions
See section 12
6.3. Methods and material for containment and cleaning up
Minor Spills
Clean up all spills immediately.
Avoid breathing dust and contact with skin and eyes.
Wear protective clothing, gloves, safety glasses and dust respirator.
Use dry clean up procedures and avoid generating dust.
Major Spills
Moderate hazard.
CAUTION: Advise personnel in area.
Alert Emergency Services and tell them location and nature of hazard.
Control personal contact by wearing protective clothing.
6.4. Reference to other sections
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
7.1. Precautions for safe handling
Safe handling
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Fire and explosion
protection
See section 5
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry area protected from environmental extremes.
Store away from incompatible materials and foodstuff containers.
7.2. Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene container.
Lined metal can, lined metal pail/ can.
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바닐린Ingredient
Material name
TEEL-1
TEEL-2
TEEL-3
Ingredient
Original IDLH
Revised IDLH
Plastic pail.
Polyliner drum.
Storage incompatibility
None known
7.3. Specific end use(s)
See section 1.2
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Control parameters
DERIVED NO EFFECT LEVEL (DNEL)
EXPOSURE PATTERN
WORKERS
GENERAL POPULATION
Short term – oral, systemic
effects
Not Available
10 mg/kg bw/day
Short term – inhalation,
local effects
10 mg/m³
Not Available
PREDICTED NO EFFECT LEVEL (PNEC)
COMPARTMENT
VALUE
Fresh Water
0.118 mg/L
Marine Water
0.0118 mg/L
Aqua
Not Available
Fresh water sediment
58.22 mg/kg sediment dw
Marine water sediment
5.822 mg/kg sediment dw
Soil
11.54 mg/kg soil dw
STP
10 mg/L
ORAL
Not Available
EMERGENCY LIMITS
바닐린
Vanilin
10 mg/m3
10 mg/m3
310 mg/m3
바닐린
Not Available
Not Available
8.2. Exposure controls
8.2.1. Appropriate
engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly
effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard ‘physically’ away from the worker and ventilation that strategically ‘adds’ and
‘removes’ air in the work environment.
8.2.2. Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of
lenses or restrictions on use, should be created for each workplace or task.
Skin protection
See Hand protection below
Hands/feet protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where
the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior
to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final
choice.
Suitability and durability of glove type is dependent on usage.
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive particles are not
present.
polychloroprene.
nitrile rubber.
butyl rubber.
Body protection
See Other protection below
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바닐린Other protection
Overalls.
P.V.C. apron.
Barrier cream.
Thermal hazards
Not Available
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or national equivalent)
8.2.3. Environmental exposure controls
See section 12
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
White or slightly yellow needle like crystal or crystalline powder
Physical state
Solid
Density
1,056 g/cm3 at 20°C
Odour
Partition coefficient
n-octanol / water
log Pow: 1,23 at 22°C
Odour threshold
Not Available
Auto-ignition temperature
(°C)
Not Available
pH (as supplied)
Not Available
Decomposition
temperature
Not Available
Melting point / freezing
point (°C)
81 – 83
Viscosity (cSt)
Not Available
Initial boiling point and
boiling range (°C)
170 °C at 20 hPa
Molecular weight (g/mol)
Not Available
Flash point (°C)
153 °C – closed cup
Taste
Not Available
Evaporation rate
Not Available
Explosive properties
Not Available
Flammability
Not flammable
Oxidising properties
Not Available
Upper Explosive Limit (%)
Not Available
Surface Tension (dyn/cm or
mN/m)
Not Applicable
Lower Explosive Limit (%)
Not Available
Volatile Component (%vol)
Not Available
Vapour pressure (kPa)
1 hPa at 107 °C；< 0,01 hPa at 25 °C
Gas group
Not Available
Solubility in water (g/L)
10 g/l at 25°C
pH as a solution (1%)
Not Available
Vapour density (Air = 1)
Not Available
VOC g/L
Not Available
9.2. Other information
Not Available
SECTION 10 STABILITY AND REACTIVITY
10.1.Reactivity
See section 7.2
10.2.Chemical stability
Product is considered stable and hazardous polymerisation will not occur.
10.3. Possibility of
hazardous reactions
See section 7.2
10.4. Conditions to avoid
See section 7.2
10.5. Incompatible materials
See section 7.2
10.6. Hazardous
decomposition products
See section 5.3
SECTION 11 TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhaled
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting.
Ingestion
The material has NOT been classified by EC Directives or other classification systems as ‘harmful by ingestion’. This is because of the lack of corroborating
animal or human evidence.
Skin Contact
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.
Eye
This material can cause eye irritation and damage in some persons.
Chronic
Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives using animal models);
nevertheless exposure by all routes should be minimised as a matter of course.
바닐린
TOXICITY
IRRITATION
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Sweet,milk fragrance and vanilla aroma
바닐린Ingredient
Persistence: Water/Soil
Persistence: Air
Ingredient
Bioaccumulation
Ingredient
Mobility PBT
Relevant available data
Not Available
Not Available
Not Available
PBT Criteria fulfilled?
Not Available
Not Available
Not Available
Intraperitoneal (mouse) LD50: 475 mg/kg[2]
Nil reported
Intraperitoneal (rat) LD50: 1160 mg/kg[2]
Oral (guinea pig) LD50: 1400 mg/kg[2]
Oral (Mouse) LD50: 1480 mg/kg[2]
Oral (rat) LD50: 1580 mg/kg[2]
Subcutaneous (Rat) LD50: 1500 mg/kg[2]
Legend:
- Value obtained from Europe ECHA Registered Substances – Acute toxicity 2.* Value obtained from manufacturer’s SDS. Unless otherwise specified data
extracted from RTECS – Register of Toxic Effect of chemical Substances
바닐린
For certain benzyl derivatives:
The members of this group are rapidly absorbed through the gastrointestinal tract, metabolised primarily in the liver, and excreted primarily in the urine either
unchanged or as conjugates of benzoic acid derivatives. At high dose levels, gut micro-organisms may act to produce minor amounts of breakdown products.
However, no adverse effects have been reported even at repeated high doses. Similarly, no effects were observed on reproduction, foetal development and
tumour potential.
Forvanillin:
Vanillingenerally does not cause irritation or sensitisation of the skin but sometimesdoes cause inflammation. It causes positive reactions to people already
sensitisedto Balsam of Peru, and is considered a secondary allergen. It is not consideredto cause reproductive toxicity or toxic effects to the embryo. Vanillin
doesnot cause birth defects.
Miosis, somnolence, muscle weakness, coma, respiratory stimulation, maternal effects involving ovaries, fallopian tubes, uterus, cervix and vagina recorded.
Legend:
– Data available but does not fill the criteria for classification
– Data required to make classification available
– Data Not Available to make classification
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